|
|
3-hydroxypimeloyl-CoA + NAD+ <=> H+ + NADH + 3-oxopimeloyl-CoA
|
1.1.1.259
3-hydroxypimeloyl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
|
–
–
|
|
BRENDA:
BR22610
KEGG:
R05305
MetaCyc:
1.1.1.259-RXN
|
|
|
|
(S)-3-hydroxybutyryl-CoA <=> H2O + crotonyl-CoA
|
1.3.8.7
medium-chain acyl-CoA dehydrogenase
4.2.1.116
3-hydroxypropionyl-CoA dehydratase
4.2.1.150
short-chain-enoyl-CoA hydratase
4.2.1.17
enoyl-CoA hydratase
|
–
–
–
–
|
|
BRENDA:
BR51003
KEGG:
R03026
MetaCyc:
RXN-11667;
RXN-15014
SABIO-RK:
2876
|
|
|
|
2-hydroxy-6-oxocyclohexane-1-carbonyl-CoA + H2O <=> 3-hydroxypimeloyl-CoA + H+
|
3.7.1.21
6-oxocyclohex-1-ene-1-carbonyl-CoA hydratase
|
–
|
|
BRENDA:
BR50996
KEGG:
R05593
MetaCyc:
RXN-15013
|
|
|
|
cyclohexanecarboxyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> cyclohex-1-ene-1-carbonyl-CoA + reduced_flavodoxin
|
1.3.8.11
cyclohexane-1-carbonyl-CoA dehydrogenase (electron-transfer flavoprotein)
|
–
|
|
MetaCyc:
R282-RXN
|
|
|
|
6-hydroxycyclohex-1-ene-1-carbonyl-CoA <=> cyclohexa-1,5-diene-1-carbonyl-CoA + H2O
|
4.2.1.100
cyclohexa-1,5-dienecarbonyl-CoA hydratase
|
–
|
|
BRENDA:
BR29123
KEGG:
R05597
MetaCyc:
4.2.1.100-RXN
|
|
|
|
acetyl-CoA + crotonate <=> acetate + crotonyl-CoA
|
2.8.3
2.8.3.1
propionate CoA-transferase
2.8.3.12
glutaconate CoA-transferase
2.8.3.9
butyrate---acetoacetate CoA-transferase
|
–
–
–
–
|
|
BRENDA:
BS358828
MetaCyc:
RXN-15008
SABIO-RK:
13019
|
|
|
|
glutaryl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> glutaconyl-CoA + reduced_flavodoxin
|
not assigned
|
–
|
|
MetaCyc:
GLUTARYL-COA-DEHYDROG-RXN
|
|
|
|
3-oxopimeloyl-CoA + CoA <=> glutaryl-CoA + acetyl-CoA
|
2.3.1
2.3.1.16
acetyl-CoA C-acyltransferase
|
–
–
|
|
KEGG:
R05586
MetaCyc:
RXN-8032
|
|
|
|
cyclohexanecarboxyl-CoA + H2O <=> cyclohexanecarboxylate + CoA + H+
|
3.1.2
|
–
|
|
MetaCyc:
RXN-15010
|
|
|
|
6-hydroxycyclohex-1-ene-1-carbonyl-CoA + NAD+ <=> H+ + 6-oxocyclohex-1-ene-1-carbonyl-CoA + NADH
|
1.1.1.368
6-hydroxycyclohex-1-ene-1-carbonyl-CoA dehydrogenase
|
–
|
|
BRENDA:
BR50929
KEGG:
R05581
MetaCyc:
HADTHAUERA-RXN
|
|
|
|
6-oxocyclohex-1-ene-1-carbonyl-CoA + H2O <=> 2-hydroxy-6-oxocyclohexane-1-carbonyl-CoA
|
3.7.1.21
6-oxocyclohex-1-ene-1-carbonyl-CoA hydratase
|
–
|
|
BRENDA:
BR50995
KEGG:
R10696
MetaCyc:
RXN-15012
|
|
|
|
cyclohex-1-ene-1-carbonyl-CoA + oxidized_electron_transfer_flavoprotein + H+ <=> cyclohexa-1,5-diene-1-carbonyl-CoA + reduced_flavodoxin
|
1.3.8.10
cyclohex-1-ene-1-carbonyl-CoA dehydrogenase
|
–
|
|
MetaCyc:
R265-RXN
|
|
|
|
(S)-3-hydroxybutyryl-CoA + NAD+ <=> acetoacetyl-CoA + NADH + H+
|
1.1.1.178
3-hydroxy-2-methylbutyryl-CoA dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
1.1.1.36
acetoacetyl-CoA reductase
|
–
–
–
|
|
BRENDA:
BS188053
KEGG:
R01975
MetaCyc:
RXN-11662
SABIO-RK:
2018
|
|
|
|
glutaconyl-CoA + H+ <=> CO2 + crotonyl-CoA
|
1.3.8.6
glutaryl-CoA dehydrogenase (ETF)
6.4.1.4
methylcrotonoyl-CoA carboxylase
7.2.4.5
glutaconyl-CoA decarboxylase
|
–
–
–
|
|
BRENDA:
BR50094
KEGG:
R03028
MetaCyc:
GLUTACONYL-COA-DECARBOXYLASE-RXN
SABIO-RK:
2878
|
|
|
|
acetyl-CoA <=> acetoacetyl-CoA + CoA
|
1.1.1.34
hydroxymethylglutaryl-CoA reductase (NADPH)
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.9
acetyl-CoA C-acetyltransferase
|
–
–
–
–
–
|
|
BRENDA:
BR44092
KEGG:
R00238
MetaCyc:
ACETYL-COA-ACETYLTRANSFER-RXN
SABIO-RK:
531
|
|